Crystal engineering of copper(I) and silver(I) π-complexes with 1,2,4-triazoles allyl derivatives.

Автор(и)

  • O. R. Hordiichuk Ivan Franko National University of Lviv, 79005, Lviv, Kyryla i Mefodiya Str. 6
  • Yu. I. Slyvka Ivan Franko National University of Lviv, 79005, Lviv, Kyryla i Mefodiya Str. 6
  • M. G. Mys’kiv Ivan Franko National University of Lviv, 79005, Lviv, Kyryla i Mefodiya Str. 6

Анотація

A great variety of Cu(I) and Ag(I) π-complexes with allyl-derivatives of numerous acyclic and heterocyclic ligands has been investigated over the last decades. As a result, many aspects of the influence of ligand structure, anion type and synthetic conditions on π-complexes crystal structure formation and on the effectiveness of the M(I)–(C═C) (M = Cu, Ag) interaction were studied. Nevertheless, much more still remains unexplored as it is evidenced by recent interesting results such as the discovery of new inorganic structural fragments, obtaining the first π-complexes with a number of anions, synthesis of the unique heterometallic complexes. This was made possible by the development of new synthetic approaches that allow the obtaining of Cu(I) and Ag(I) π-complexes in the form of high-quality single crystals by alternating-current electrochemical method or by direct interaction. This class of compounds is interesting because of their catalytic, biological, photoluminescent and optoelectronic properties.

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