Novel copper(I) π-complexes with allyl derivatives of disubstituted pseudothiohydantoins: synthesis, crystal structure and NLO properties.
Автор(и)
A. A. Fedorchuk
Department of Inorganic Chemistry, Ivan Franko National University of Lviv,
Kyryla i Mefodiya Str., 6, 79005, Lviv, Ukraine
Yu. I. Slyvka
Department of Inorganic Chemistry, Ivan Franko National University of Lviv,
Kyryla i Mefodiya Str., 6, 79005, Lviv, Ukraine
I. V. Kityk
Institute of Optoelectronics and Measuring Systems, Faculty of Electrical Engineering,
Czestochowa University of Technology,
17 Armii Krajowej Str., 42-200 Czestochowa, Poland
M. G. Mys’kiv
Department of Inorganic Chemistry, Ivan Franko National University of Lviv,
Kyryla i Mefodiya Str., 6, 79005, Lviv, Ukraine
Анотація
The structure of compound 1 is built of dimeric tetranuclear [Cu4(dapt)2Cl4] fragments and ethanol molecules, which are located on the three-fold inversion axis and partially fill voids in the crystal structure. Central part of [Cu4(dapt)2Cl4] coordination dimer is formed by {Cu4Cl4} cluster, in which Cu atoms are bonded by bridging Cl atoms. Ligand molecule in 1 acts as tridentate chelating ligand and plays a bridged role being bonded simultaneously to the both crystallographically independent Cu atoms.
