Synthesis and crystal structure characterization of novel copper(I) π-complexes with N-ALLYL-1,2,3-triazole.
Автор(и)
A. M. Fedko
Ivan Franko National University of Lviv, Kyryla i Mefodiya 6, 79005 Lviv, Ukraine
Yu. I. Slyvka
Ivan Franko National University of Lviv, Kyryla i Mefodiya 6, 79005 Lviv, Ukraine
M. G. Mys'kiv
Ivan Franko National University of Lviv, Kyryla i Mefodiya 6, 79005 Lviv, Ukraine
Анотація
1,2,3-Triazoles, being an important type of heterocyclic compounds, have a wide range of application in different spheres, in particular, they known as photostabilizers of polymers, optical brightening agents, corrosion inhibibitors, dyestuffs. Due to their biologiacal activity they find applicantion in medicine as antibacterial, antivirus and anticancer agents. Moreover, due to triazole structure features they can mimic different functional groups, justifying their wide employment as bioisosteres. It was also investigated that triazole-based complexes with Cu(I) display NLO properties. It exploration may be useful in the study of cancer progression mechanism which is accompanied with the change of copper(I) level in damaged tissues. Since a number of copper(I) π-complexes with benzotriazole allyl derivatives has been already studied, we present in this work firstly obtained Cu(I) π-compounds with allyl derivatives of monocyclic 1,2,3-triazole.
