Nanocomposite of Pd nanoparticles with mil-101(Cr) coordination polymer for catalytic hydrogenation of quinoline.
Автор(и)
V. M. Asaula
L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
H. H. Repich
Technische Universität Dresden, Die Fakultät Chemie und Lebensmittelchemie
A. M. Mishura
L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
K. S. Gavrilenko
Enamine Ltd
ChemBioCenter, National Taras Shevchenko University of Kyiv
S. V. Ryabukhin
Enamine Ltd
D. M. Volochnyuk
ChemBioCenter, National Taras Shevchenko University of Kyiv
Institute of Organic Chemistry of the NAS of Ukraine
S. V. Kolotilov
L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
Анотація
Reactions of catalytic hydrogenation of heterocycles are very important for modern organic chemistry and chemical manufacturing for synthesis of active pharmaceutical ingredients and compounds for agrochemistry. Pd-containing catalysts are widely used for such processes, and among them composites of porous coordination polymers (PCPs) with Pd nanoparticles (NPs) are considered as promising objects. The advantages of such systems include thermal and hydrolytic stability, as well as microporosity which prevents NPs agglomeration and can give rise to size-selectivity of the catalyst.
