Copper(I) π-complexes with allyl[(4,6-dimethylpyrimidin-2-yl)sulfanil]acetate: synthesis, crystal structure and nlo properties.
Автор(и)
H. O. Andrusiv
Department of Inorganic Chemistry, Ivan Franko National University of Lviv
Yu. I. Slyvka
Department of Inorganic Chemistry, Ivan Franko National University of Lviv
E. A. Goreshnik
Department of Inorganic Chemistry and Technology,“Jožef Stefan” Institute
M. G. Mys’kiv
Department of Inorganic Chemistry, Ivan Franko National University of Lviv
Анотація
Derivatives of pyrimidine have been a field of intensive studies in pharmaceutics, biochemistry and synthetic organic chemistry over the last decades. But complexes of allyl derivatives of pyrimidine with copper(I) are not well researched, eventhough complexes with ligands containing conformationally rigid heterocyclic fragments and flexible allyl groups in recent years have become a fild of interest in crystal engineering. In our work we investigated structural behavior of copper(I) π-complexes with allyl[(4,6-dimethylpyrimidin-2- yl)sulfanil]acetate (L).
