Mechanism of formation of polymeric phosphates at the heat treatment of crystallohydrates of divalent metals.
Автор(и)
N. M. Antraptseva
National University of Life and Environmental Sciences of Ukraine
S. A. Korechko
National University of Life and Environmental Sciences of Ukraine
L. B. Koval
V. I. Vernadskii Institute of General and Inorganic Chemistry Ukrainian National
Academy of Sciences
Анотація
By researches of double phosphates MII 1-xMII x(H2PO4)2·2H2О (MII=Mg, Mn, Co, Zn), for the first time it is established, that one of peculiarities of their thermolysis is ability to the intramolecular hydrolysis. As a result of this process the dihydrophosphates thermolysis is accompanied by formation of free phosphoric acids, which expose to condensation and take part in formation of polymeric phosphates.
