Catalytic reductive amination and hydrogenation of benzaldehyde.

Автор(и)

  • V. M. Asaula L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • I. V. Kushchenko L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • K. S. Gavrilenko Enamine Ltd ChemBioCenter, National Taras Shevchenko University of Kyiv
  • O. O. Pariiska L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • S. V. Ryabukhin Enamine Ltd
  • D. M. Volochnyuk ChemBioCenter, National Taras Shevchenko University of Kyiv Institute of Organic Chemistry of the NAS of Ukraine
  • S. V. Kolotilov L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine

Анотація

Reactions of catalytic amination of carbonyl compounds are widely used for production of amines. In particular, interaction of benzaldehyde with aliphatic amines at presence of H2 can lead to N-benzyl-N-alkylamines. Such reactions are usually catalyzed by compounds, containing platinum group metals (PGM). Search of PGM-free catalysts for such transformations is important task of modern physical chemistry. The aim of this study was to check catalytic activity of the composites, containing Co oxides and N-doped carboneous materials, in catalytic reductive amination of benzaldehyde with i-propylamine.

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