Reaching high-spin chiral molecular materials
Анотація
Chiral π-conjugated materials have recently emerged as a new direction in material science due to their specific interaction with circularly polarized light and the potential of the latter in organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs) and magnets[1]. While extensive researches have been focusing on organic closed-shell chiral dyes, a few attention has been given to their open-shell counterparts due to their low configurational stability and high chemical reactivity [2].
Посилання
R. Naaman, Y. Paltiel and D. H. Waldeck, Nat. Rev. Chem. 2019, 3, 250–260.
a) Sugawara, T. et al., Chem. Soc. Rev. 2011, 40 (6), 3105–3118; b) A. Rajca, J. Am. Chem. Soc. 2019, 141, 17287–172943.
a) Kasemthaveechok, S. et al., J. Am. Chem. Soc. 2020, 142 (48), 20409–20418; b) Kasemthaveechok, S. et al., J. Am. Chem. Soc. 2022, 144, 7253–7263.
