Synthesis and crystal structure of sodium heteropoly decatungstoterbate(III) Nа<sub>9</sub> [Tb(W<sub>5</sub>O<sub>18</sub>)<sub>2</sub>]·34H<sub>2</sub>O.

Автор(и)

  • O. Yu. Mariichak Vasyl’ Stus Donetsk National University
  • G. M. Rozantsev Vasyl’ Stus Donetsk National University
  • S. V. Radio Vasyl’ Stus Donetsk National University

Анотація

In present study the procedure for successful synthesis of sodium heteropoly decatungstoterbate(III), Na9[Tb(W5O18)2]·34H2O, from acidified up to Z=ν(H+ )/ν(WO4 2– ) = 0.80 solution of sodium tungstate with a ratio of ν(Tb):ν(W) = 1:10 from aqueous-acetone media was elaborated.

Посилання

Ozeki T., Takahashi M., Yamase T. // Acta Cryst. – 1992. – Vol. C48. – P.1370–1374. DOI: 10.1107/S0108270192000155

Vonci M., Giansiracusa M.J., Van den Heuvel W., Gable R.W., Moubaraki B., Murray K.S., Yu D., Mole R.A., Soncini A., Boskovic C. // Inorg. Chem. – 2017. – Vol. 56, No. 1. – P. 378–394. DOI: 10.1021/acs.inorgchem.6b02312

##submission.downloads##

Номер

2019

Розділ

Неорганічна хімія