Catalytic activity of Cu(II) and Fe(III) porous coordination polymers in oxidation of 1,2,3,4-tetrahydro-1-naphthol by hydrogen peroxide.

Автор(и)

  • E. N. Abdullaev L. V. Pisarzhevskii Institute of Physical Chemistry of the NAS of Ukraine
  • M. O. Ivanytsya L. V. Pisarzhevskii Institute of Physical Chemistry of the NAS of Ukraine Enamine Ltd
  • A. M. Mishura L. V. Pisarzhevskii Institute of Physical Chemistry of the NAS of Ukraine
  • K. S. Gavrilenko Enamine Ltd ChemBioCenter, National Taras Shevchenko University of Kyiv
  • S. V. Kolotilov L. V. Pisarzhevskii Institute of Physical Chemistry of the NAS of Ukraine

Анотація

Porous coordination polymers (PCPs) of 3d metals are considered as promising catalysts of oxidation reactions for fine organic synthesis. Use of such catalysts allows reactions carrying out in conditions of heterogeneous catalysis (including use of flow reactors), which simplifies separation of the catalyst and product purification. Determination of factors, which influence catalytic activity of such systems, is important task of modern physical chemistry and catalysis.

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