Synthesis and electrochemical hydrogenation of the Tb2Co16Mg0.5Al0.5 phase

Автор(и)

  • I. A. Stetskiv Department of Inorganic Chemistry, Ivan Franko National University of Lviv
  • V. M. Kordan Department of Inorganic Chemistry, Ivan Franko National University of Lviv
  • I. I. Tarasiuk Department of Inorganic Chemistry, Ivan Franko National University of Lviv
  • V. V. Pavlyuk Department of Inorganic Chemistry, Ivan Franko National University of Lviv

Анотація

Hexagonal structure type Th2Ni17 (hP38, P63/mmc) is a derived type of the CaCu5 (hP6, P6/mmm) structure, which is formed by tripling of the cell with the replacement of one large rare-earth metal atom by two smaller transition metal atoms. Successful electrochemical hydrogenation of compounds based on terbium and 3d-transition metals belonging to Th2Ni17 structure type has been previously reported. Partial replacement of cobalt with other elements leads to improved hydrogen adsorption properties.

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Опубліковано

2021-04-21

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Неорганічна хімія