Crystal structure of dimeric cu(I) halides π-complexes with disubstituted derivitives of pseudothiohydantoin.

Автор(и)

  • A. A. Fedorchuk Ivan Franko National University of Lviv
  • Yu. I. Slyvka Ivan Franko National University of Lviv
  • M. G. Mys’kiv Ivan Franko National University of Lviv

Анотація

Thiazolidinone derivatives possess luminescence and nonlinear-optical (NLO) properties and one of the ways to improve those properties, in particular, is the formation of corresponding coordination compounds. Previously, we have synthesized and determined the crystal structure of a novel copper(I) π-complex [Cu4(dapt)2Cl4]·0.38EtOH with diallyl derivative of pseudothiohydantoin (3-allyl-2-(allylimino)-1,3-thiazolidin-4-one) and have studied its photoinduced nonlinear optical properties, namely – laser stimulated second order susceptibility, which achieves a magnitude of 2.2 pm/V.

Біографії авторів

A. A. Fedorchuk, Ivan Franko National University of Lviv

Department of Inorganic Chemistry

Yu. I. Slyvka, Ivan Franko National University of Lviv

Department of Inorganic Chemistry

M. G. Mys’kiv, Ivan Franko National University of Lviv

Department of Inorganic Chemistry

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