Crystal structure of dimeric cu(I) halides π-complexes with disubstituted derivitives of pseudothiohydantoin.
Authors
A. A. Fedorchuk
Ivan Franko National University of Lviv
Yu. I. Slyvka
Ivan Franko National University of Lviv
M. G. Mys’kiv
Ivan Franko National University of Lviv
Abstract
Thiazolidinone derivatives possess luminescence and nonlinear-optical (NLO) properties and one of the ways to improve those properties, in particular, is the formation of corresponding coordination compounds. Previously, we have synthesized and determined the crystal structure of a novel copper(I) π-complex [Cu4(dapt)2Cl4]·0.38EtOH with diallyl derivative of pseudothiohydantoin (3-allyl-2-(allylimino)-1,3-thiazolidin-4-one) and have studied its photoinduced nonlinear optical properties, namely – laser stimulated second order susceptibility, which achieves a magnitude of 2.2 pm/V.
Author Biographies
A. A. Fedorchuk, Ivan Franko National University of Lviv
Department of Inorganic Chemistry
Yu. I. Slyvka, Ivan Franko National University of Lviv
Department of Inorganic Chemistry
M. G. Mys’kiv, Ivan Franko National University of Lviv
