Synthesis of Co(II) complex with ligand of Salen type bearing "free" carboxy-groups and its catalytic activity in asymmetric oxidation of methylphenylsulfide

Автор(и)

  • Y. L. Lishchenko Enamine Ltd, National Taras Shevchenko University of Kyiv
  • S. O. Sotnik Enamine Ltd, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • S. V. Kolotilov Enamine Ltd, L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, National Taras Shevchenko University of Kyiv
  • K. S. Gavrilenko National Taras Shevchenko University of Kyiv
  • S. V. Ryabukhin Enamine Ltd, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, National Taras Shevchenko University of Kyiv
  • D. M. Volochnyuk Enamine Ltd, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, National Taras Shevchenko University of Kyiv

Анотація

Recently, the metal complexes with ligands of Salen type have been actively studied as catalysts for various organic reactions. Selective sulfoxidation of sulfides to chiral sulfoxides is one of the important ways to obtain useful compounds that have been widely used in organic synthesis and medical chemistry. Some metal-salen complexes of Mn(III) and Ti(IV) showed catalytic activity in selective sulfoxidation of sulfides, but this processes were carried out in environmentally non-friendly solvents, such as chlorinated ones. There were multiple attempts to replace organic solvents by water.

##submission.downloads##

Опубліковано

2022-07-07

Номер

Розділ

Органічна хімія