Nanocomposites based on Co nanoparticles for catalytic hydrogenation of quinoline

Authors

  • I. V. Tarasova L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Enamine Ltd
  • V. V. Subotin L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Enamine Ltd
  • O. O. Pariiska L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • S. V. Ryabukhin Enamine Ltd, Institute of high technologies, National Taras Shevchenko University of Kyiv
  • D. M. Volochnyuk Enamine Ltd, Institute of high technologies, National Taras Shevchenko University of Kyiv, Institute of Organic Chemistry of the NAS of Ukraine
  • S. V. Kolotilov L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Institute of high technologies, National Taras Shevchenko University of Kyiv

Abstract

Development of new catalysts for hydrogenation of heterocyclic compounds is important task of physical and organic chemistry, because such systems are highly demanded for synthesis of active pharmaceutical ingredients, effective substances for plant protection etc. The composites based on 3d metal nanoparticles can have high catalytic activity in such processes, and thus are considered as an alternative for the catalysts based on Pt and Pd.
The aim of this work was to study the influence of the composition and structure of composites of graphene-like carbon and nanosized 3d metals, prepared by pyrolysis of metal complexes on the different carriers, on their catalytic activity in quinoline hydrogenation.

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Published

2023-04-04

Issue

2023

Section

Organic Chemistry