Structure of Pd/C composites and their catalytic properties in hydrogenation of diene carboxylates

Authors

  • E. V. Verner Enamine Ltd., L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • V. V. Subotin Enamine Ltd., L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • B. V. Vashchenko Enamine Ltd., Taras Shevchenko National University of Kyiv
  • V. M. Asaula L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • M. O. Ivanytsya Enamine Ltd., L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • O. V. Shvets L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine
  • E. N. Ostapchuk Enamine Ltd., Taras Shevchenko National University of Kyiv
  • O. O. Grygorenko Enamine Ltd., Taras Shevchenko National University of Kyiv
  • S. V. Ryabukhin Enamine Ltd., Taras Shevchenko National University of Kyiv, Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • D. M. Volochnyuk Enamine Ltd., Taras Shevchenko National University of Kyiv, Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • S. V. Kolotilov Enamine Ltd., L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine,, Taras Shevchenko National University of Kyiv

Abstract

A series of palladium-containing composites, i.e. four Pd/C and three "Pd(OH)2 " /C (Pearlman’s catalysts, where Pd(OH)2 indicated hydrated PdO), was prepared using modified common approaches to deposition of Pd or PdO on the charcoal. The composites were characterized by transmission and scanning electron microscopy (TEM and SEM), powder Xray diffraction, and low-temperature N2 adsorption.

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Published

2023-04-06

Issue

2023

Section

Physical Chemistry