Electrochemical synthesis of the TiAl<sub>1-x</sub>Li<sub>x</sub>phase.

Authors

  • V. M. Kordan Department of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mefodiya St., 79005 Lviv, Ukraine
  • O. R. Zhyshkovych Department of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mefodiya St., 79005 Lviv, Ukraine
  • O. Ya. Zelinska Department of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mefodiya St., 79005 Lviv, Ukraine
  • V. V. Pavlyuk Department of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mefodiya St., 79005 Lviv, Ukraine

Abstract

Intermetallic compounds containing large voids can be used as potential electrode materials in Li-ion batteries. Our previous investigations showed that the size of the voids and the amount of intercalated Li depends on the transition metal. The type of lithiation reaction (inclusion or substitution) and the type of solid solution formed as a result of lithiation depends on the p-element.

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Inorganic Chemistry