Copper(I) halide coordination compounds with N-phenylurea allyl derivatives.
Authors
А. I. Yanchak
Ivan Franko National University of Lviv
Yu. I. Slyvka
Ivan Franko National University of Lviv
E. A. Goreshnik
“Jožef Stefan” Institute
M. G. Mys’kiv
Ivan Franko National University of Lviv
Abstract
It has been demonstrated earlier that allyl derivatives of urea successfully form crystalline coordination compounds with Cu(I) and Ag(I) in which olefin fragments are bound to metal atoms. In search for materials with prominent NLO properties two new ligands of this type (Fig. 1) – 3-phenyl-1,1-diallylurea (dapu) and 1-phenyl-3-allylurea (mapu) – were prepared via condensation of phenyl isocyanate with respective amines.
Author Biographies
А. I. Yanchak, Ivan Franko National University of Lviv
Department of Inorganic Chemistry
Yu. I. Slyvka, Ivan Franko National University of Lviv
Department of Inorganic Chemistry
E. A. Goreshnik, “Jožef Stefan” Institute
Department of Inorganic Chemistry and Technology
M. G. Mys’kiv, Ivan Franko National University of Lviv
