Comparing reactivity of phthalimide-N-oxyl and quinolineimide-N-oxyl radicals toward the C-H bonds of substituted benzyl alcohols.
Authors
I. O. Hordieieva
Vasyl’ Stus Donetsk National University
O. O. Zosenko
Vasyl’ Stus Donetsk National University
O. V. Kushch
Vasyl’ Stus Donetsk National University
L. M. Litvinenko Institute of Physico-organic and Coal Chemistry, NAS of Ukraine
A. N. Shendrik
Vasyl’ Stus Donetsk National University
Abstract
Benzyl alcohol and its substituted derivatives are model compounds for investigation of lignin oxidation process using laccase/N-OH mediator system. The activation of aliphatic C-H bonds with the participation of N-oxyl radicals is an important stage in the oxidation of benzyl alcohols in the presence of NOH-compounds.
Author Biographies
I. O. Hordieieva, Vasyl’ Stus Donetsk National University
Faculty of Chemistry, Biology and Biotechnologies
O. O. Zosenko, Vasyl’ Stus Donetsk National University
Faculty of Chemistry, Biology and Biotechnologies
O. V. Kushch, Vasyl’ Stus Donetsk National University
L. M. Litvinenko Institute of Physico-organic and Coal Chemistry, NAS of Ukraine
Faculty of Chemistry, Biology and Biotechnologies
A. N. Shendrik, Vasyl’ Stus Donetsk National University
