New Lu(III)-containing heteropoly salt with peacock–weakley type anion Na<sub>9</sub>[Lu(W<sub>5</sub>O<sub>18</sub>)<sub>2</sub>]·42H<sub>2</sub>O: synthesis and crystal structure

Authors

  • Vasyl' Stus Donetsk National University
  • Vasyl' Stus Donetsk National University
  • Vasyl' Stus Donetsk National University

Abstract

New neutral sodium salt with Peacock-Weakley type anion Na9[Lu(W5O18)2]·42H2O and Lu(III) as heteroatom was synthesized using procedure, elaborated in (Mariichak O.Yu., et al. Patent of Ukraine No. 121322, 2017). The crystalline compound was obtained from the aqueous solution acidified up to Z=0.80 (Z=ν(H+ )/ν(WO4 2- )) from Lu(NO3)3–Na2WO4–HNO3– H2O system.

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Published

2021-04-20

Issue

Section

Inorganic Chemistry